Chloridotris(4-chlorobenzyl-κC)(triphenylarsine oxide-κO)tin(IV)
نویسندگان
چکیده
The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(3)Cl(C(18)H(15)AsO)], shows a distorted C(3)ClOSn trigonal bipyramidal coordination; the axial O-Sn-Cl angle is 170.22 (4)°.
منابع مشابه
Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate
The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0 (3)° and O-Sn-O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent mol-ecule could reason...
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The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent mol-ecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octa-hedral coordination environment. One chloro-benzyl substituent is disordered in each mol-ecule in 0.5:0.5 and 0.778 (2):0.222 (2) r...
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The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl a...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009